Product ID:UNLEADED GASOLINE
MSDS Date:01/14/1992
FSC:9130
NIIN:01-282-2844
MSDS Number: BMTSJ

GLOBAL PETROLEUM CORP

800 SOUTH STREET
WALTHAM, MA 02254-9161
US

Emergency Phone: 617-769-2705/800-424-9300(CHEMTREC)

Info Phone: 617-769-2705

Preparer: RON KENNY

Cage: 1CU79

GLOBAL PETROLEUM CORP

9161 WALTHAM, MA 02254 US

Telephone: 617-398-4129

Cage: 1CU79

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 0 - 25%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 0 - 25%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: <5.0%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE & CHRONIC-EYE:MODERATE
IRRITATION.SKIN:PROLONGED/REPEATED CONTACT CAN CAUSE IRRITATION &
DERMATITIS.INHALE:MAY CAUSE NOSE,THROAT,RESPIRATORY TRACT
IRRITATION,LIVER & KIDNEY DAMAGE,CNS DEPRESSION
(GIDDINESS,HEADACHE,DIZZINESS,NAUSEA EVEN DEATH).ORAL:MAY BE
HARMFUL/FATAL.MAY RESULT IN VOMITING.ASPIRATION HAZARD.
Explanation of Carcinogenicity:CONTAINS BENZENE
Effects of Overexposure:MODERATE EYE IRRITATION. PROLONGED/REPEATED
SKIN CONTACT CAN CAUSE IRRITATION & DERMATITIS. INHALATION MAY
CAUSE NOSE, THROAT, RESPIRATORY TRACT IRRITATION, LIVER & KIDNEY
DAMAGE, CNS DEPRESSION (GIDD INESS, HEADACHE, DIZZINESS, NAUSEA
EVENDEATH). ORALLY MAY BE HARMFUL OR FATAL. MAY CAUSE VOMITING.
ASPIRATION HAZARD.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS OR EYE PROBLEMS OR IMPAIRED LIVER, KIDNEY OR RESPIRATORY
FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.

First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST.SKIN:WASH WITH SOAP
& WATER.EYE:FLUSH WITH WATER FOR 15 MINUTES,HOLDING EYELIDS
OPEN.INHALED:REMOVE TO FRESH AIR & PROVIDE OXYGEN/CPR IF
NEEDED.ORAL:DO NOT IN DUCE VOMITING.IF VOMITING OCCURS,KEEP HEAD
BELOW HIPS TO PREVENT ASPIRATION.CALL A PHYSICIAN.NOTE TO
PHYSICIAN:IF MORE THAN 2 ML/KG HAS BEEN INGESTED,EMESIS SHOULD BE
INDUCED WITH MEDICAL SUPERVISION.

Flash Point:-40F,-40C
Lower Limits:1.3
Upper Limits:7.6
Extinguishing Media:WATER SPRAY,CO2,FOAM/DRY CHEMICAL. DO NOT USE A
DIRECT STREAM OF WATER. PRODUCT WILL FLOAT & CAN BE REIGNITED ON
SURFACE
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING & NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN
THE POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:VAPOR IS HEAVIER THAN AIR AND CAN TRAVEL
CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK.
EXTREMELY FLAMMABLE. DO NOT WELD,HEAT,DRILL NEARBY.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT.ELIMINATE SOURCES OF
IGNITION.VENTILATE THE AREA.STOP LEAK IF POSSIBLE.CONTAIN THE
SPILL.PICK UP LARGE SPILL WITH NON-SPARKING TOOLS;SMALL
SPILLS/RESIDUE WITH ABSORBENT MATER IAL.PLACE IN NON-LEAK
CONTAINERS.CONTAINRUN-OFF.
Neutralizing Agent:NONE

Handling and Storage Precautions:STORAGE-NFPA CLASS 1A STORAGE.KEEP
AWAY FROM FLAME,SPARKS & HOT SURFACES.
Other Precautions:EMPTY CONTAINER MAY CONTAIN TOXIC,
FLAMMABLE/COMBUSTIBLE OR EXPLOSIVE RESIDUE OR VAPORS. DO NOT CUT,
GRIND, WELD, DRILL OR REUSE CONTAINERS UNLESS ADEQUATE PRECAUTIONS
ARE TAKEN AGAINST THESE HAZARD. AVOID CONTACT WITH EYES AND SKIN.

Respiratory Protection:UNDER CONDITIONS OF POTENTIAL HIGH EXPOSURE, THE
USE OF A NIOSH-APPROVED RESPIRATOR IS RECOMMENDED. USE EITHER AN
ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING RESPIRATOR FOR
ORGANIC VAPORS.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL - EXPLOSION PROOF)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:IMPERVIOUS
Eye Protection:CHEMICAL SAFETY GLASSES/GOGGLES
Other Protective Equipment:EYE WASH STATION, QUICK DRENCH SHOWER AND
IMPERVIOUS CLOTHING
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health

HCC:F1
Boiling Pt:B.P. Text:55.0F,12.8C
Vapor Pres:7 - 14.5
Vapor Density:3.5
Spec Gravity:0.72
Solubility in Water:NEGLIGIBLE
Appearance and Odor:LIGHT AMBER COLOR, CLEAR AND BRIGHT LIQUID.
HYDROCARBON ODOR

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Stability Condition to Avoid:VAPOR ACCUMULATION, HIGH HEAT, SPARKS,
STATIC ELECTRICITY, OPEN FLAMES AND OTHER SOURCES OF IGNITION
Hazardous Decomposition Products:CARBON MONOXIDE AND OTHER UNIDENTIFIED
ORGANIC COMPOUNDS CAN BE FORMED UPON COMBUSTION

Waste Disposal Methods:DISPOSE OF IN APPROVED DISPOSAL SITE. FREE
LIQUID IGNITABLE WASTES ARE BANNED FROM DISPOSAL BY LAND FILLING OR
IN CONTAINERS. PRODUCT RECOVERY AND RECYCLING ARE RECOMMENDED WHERE
POSSIBLE. OBSERVE ALL LOCAL, STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.